Two reactions of allylic alcohols catalysed by ruthenium cyclopentadienyl complexes with didentate phosphine ligands: isomerisation and ether formation

Autor:	Matteo Vailati, Robert C. van der Drift, Eite Drent, Elisabeth Bouwman
Rok vydání:	2000
Předmět:	Allylic rearrangement Diene Process Chemistry and Technology chemistry.chemical_element Ether Alcohol Medicinal chemistry Catalysis Ruthenium chemistry.chemical_compound Cyclopentadienyl complex chemistry Organic chemistry Physical and Theoretical Chemistry Allyl alcohol Phosphine
Zdroj:	Journal of Molecular Catalysis A: Chemical. 159:163-177
ISSN:	1381-1169
DOI:	10.1016/s1381-1169(00)00221-1
Popis:	The activity of chloro(η5-cyclopentadienyl)(didentate phosphine)ruthenium(II) complexes in the catalysis of two types of reaction with allylic alcohols is described. The isomerisation of 3-buten-2-ol to butanone (MEK) and allyl alcohol to propanal proceeds at high rates. A trend in catalytic activity is observed upon variation of the carbon-chain length in the didentate phosphine ligand: dppm
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f481b45b5b26953368993a3bd8d0d652 https://doi.org/10.1016/s1381-1169(00)00221-1 Zobrazit plný text záznamu Full Text from ScienceDirect