Isobaric vapor liquid equilibria data for the binary system (glycidyl butyrate + acetone, glycidyl butyrate + carbon tetrachloride, glycidyl butyrate + chloroform) at atmospheric pressure 101 kPa
| Autor: | Qingyi Meng, Rui Zhang, Yingyu Gao, Qiang Huang, Chunlan Ban |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Activity coefficient
UNIQUAC Chloroform Analytical chemistry 02 engineering and technology Butyrate 010402 general chemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound 020401 chemical engineering chemistry Azeotrope Acetone Non-random two-liquid model Organic chemistry Binary system 0204 chemical engineering Physical and Theoretical Chemistry |
| Zdroj: | Russian Journal of Physical Chemistry A. 90:1789-1797 |
| ISSN: | 1531-863X 0036-0244 |
| DOI: | 10.1134/s0036024416090260 |
| Popis: | Isobaric vapor liquid equilibria (VLE) for the binary mixtures of glycidyl butyrate(1) + acetone(2), glycidyl butyrate(1) + carbon tetrachloride(2) and glycidyl butyrate(1) + chloroform(2) at 101 kPa were studied. The experimental data were satisfactorily correlated with the models of Wilson, NRTL and UNIQUAC activity coefficients. The activity coefficients for the equilibrium data were obtained by the nonlinear least square method. The average relative deviations between experimental temperatures and calculated temperatures by the Wilson, NRTL and UNIQUAC models were 0.16, 0.16, 0.23% for glycidyl butyrate(1) + chloroform( 2), 0.38, 0.12, 0.27% for glycidylbutyrate(1) + carbon tetrachloride(2), and 0.67, 0.13, 0.54% for glycidyl butyrate(1) + acetone(2). Azeotrope behavior was not found for these systems. The thermodynamic consistency of the correlations was checked by the Herrington’s area test. |
| Databáze: | OpenAIRE |
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