Assisted electrooxidation of the phenylchromiumtricarbonyl moiety in mixed phenylchromiumtricarbonyl-ferrocenyl compounds

Autor:	C. Degrand, J. Besançon, A. Radecki-Sudre
Rok vydání:	1984
Předmět:	chemistry.chemical_compound Depolarizer Ferrocene Chemistry Organic solvent Inorganic chemistry Moiety Conjugated system Cyclic voltammetry Electrochemistry Medicinal chemistry Metallocene
Zdroj:	Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 160:199-207
ISSN:	0022-0728
DOI:	10.1016/s0022-0728(84)80125-4
Popis:	In compounds which contain both phenylchromiumtricarbonyl (Bct) and ferrocentyl (Fc) groups, an induced electrooxidation of the Bct moiety occurs in N,N-dimethylformamide in the cases in which the two groups are conjugated. The efficiency of the assisted oxidation is related to the intermediate Cr(I) species which is generated and to the distance between the Bct and Fc sites. This efficiency increases when the concentration of the depolarizer and/or the distance between the electroactive sites are decreased.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f46aa4882fad97feb53cf70850b1f7f2 https://doi.org/10.1016/s0022-0728(84)80125-4 Zobrazit plný text záznamu