Effect of Strontium-Doped Lanthanum Vanadate on Crystal Structure, Conductivity and Vanadium Valence State of a La1−x Sr x VO3 Anode in a Reducing Environment

Autor: Chi Yang Liu, Shu Yi Tsai, Kuan-Zong Fung, Chung Ta Ni
Rok vydání: 2017
Předmět:
Zdroj: Journal of Electronic Materials. 46:2301-2308
ISSN: 1543-186X
0361-5235
DOI: 10.1007/s11664-016-5268-9
Popis: La1−xSrxVO3 (where x = 0, 0.1, 0.3, 0.5, 0.7, and 1) exhibits a transition from an antiferromagnetic insulator to a paramagnetic metallic conductor and has been synthesized as a potential anode material for solid oxide fuel cells (SOFCs). La1−xSrxVO3 was synthesized by a solid-state reaction process followed by heat treatment under a reducing atmosphere (Ar:80/H2:20). X-ray diffraction (XRD) results indicate that LaVO3 was substituted with various amounts of Sr2+ in the cation sublattice. Pure LaVO3 shows an orthorhombic structure. After Sr2+ substitution, a more symmetrical cubic perovskite structure was obtained because the tolerance factor is close to 1. The valence state of the vanadium ions of the La1−xSrxVO3 was further verified by x-ray photoelectron spectroscopy (XPS). According to the XPS results, when the lanthanum ion was substituted by a strontium ion, the negatively charged defect, SrLa’, was compensated for by changing the valence of vanadium from a trivalent to a tetravalent or pentavalent state. The dependence of conduction behavior of La1−xSrxVO3 on the amount of Sr addition is discussed in terms of the hopping process with super/double exchange interaction and a charge transfer mechanism.
Databáze: OpenAIRE
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