Synthesis and characterization of two inorganic–organic hybrid polyoxometalates bridged by Keggin-type building blocks and copper(II) organonitrogen complexes

Autor:	Luo-Lan Li, Fang-Fang Dong, Liang Che, Fang Luo
Rok vydání:	2010
Předmět:	Hydrogen bond Inorganic chemistry Metals and Alloys Supramolecular chemistry chemistry.chemical_element Copper Hydrothermal circulation Catalysis Inorganic Chemistry chemistry.chemical_compound Crystallography Oxygen atom chemistry Materials Chemistry Inorganic organic Organometallic chemistry
Zdroj:	Transition Metal Chemistry. 36:125-130
ISSN:	1572-901X 0340-4285
Popis:	Two new inorganic–organic hybrid compounds, namely [Cu(dab)2]2[α-SiW12O40]·H2O (dab = 1,2-diaminobenzene) and [Cu(dafo)3]2[Cu(dafo)2(H2O)2][α-PMo12O40]2·4H2O (dafo = 4,5-diaza- fluorene-9-one) have been synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction. [Cu(dab)2]2[α-SiW12O40]·H2O exhibits an alternating 2D ladder-like structure built of [α-SiW12O40]4− and [Cu(L)2]2+ units. As the inorganic building block, the Keggin-type polyoxoanion [α-SiW12O40]4− is linked to two metal–organic complexes [Cu(dab)2]2+ through different kinds of oxygen atoms (terminal and bridging). [Cu(dafo)3]2[Cu(dafo)2(H2O)2][α-PMo12O40]2·4H2O shows an extended 3D supramolecular network via hydrogen bonding. Both complexes were characterized by physico-chemical and spectroscopic methods.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f4673fc58e7647e1d2cb0db68e50d6f5 https://doi.org/10.1007/s11243-010-9444-0 Zobrazit plný text záznamu Full text from SpringerLink