Unexpected Viability of Pyridyl Methanimine-Based Ligands for Transition-Metal-Mediated Living Radical Polymerization in Aqueous Media at Ambient Temperature

Autor:	Sébastien Perrier, F. L. G. Malet, David M. Haddleton, S. P. Armes, Xiaosong Wang
Rok vydání:	2000
Předmět:	Schiff base Polymers and Plastics Organic Chemistry Radical polymerization Photochemistry Methacrylate Macromonomer Inorganic Chemistry chemistry.chemical_compound Living free-radical polymerization chemistry Transition metal Polymerization Polymer chemistry Materials Chemistry Ethylene glycol
Zdroj:	Macromolecules. 34:162-164
ISSN:	1520-5835 0024-9297
DOI:	10.1021/ma001397u
Popis:	Pyridyl methanimine-based ligands are used in aqueous media at neutral pH for the efficient living radical polymerization of hydrophilic monomers. High conversions (>90%), good molecular weight control, and low polydispersities (Mw/Mn < 1.20) were obtained for the polymerization of monomethoxy-capped oligo(ethylene glycol) methacrylate at 20 °C; faster rates, reduced control, and higher polydispersities were obtained at elevated temperatures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f458f443e9fc470893d19344892d0251 https://doi.org/10.1021/ma001397u Zobrazit plný text záznamu