Reaction of arsenic, antimony, bismuth and sulfur fluorides with (t-butylthio) trimethylsilane

Autor:	C.J. Willis, O.C. Vaidya, A.F. Janzen
Rok vydání:	1981
Předmět:	inorganic chemicals Polymers and Plastics Inorganic chemistry chemistry.chemical_element Trimethylsilane Mass spectrometry Sulfur Bismuth chemistry.chemical_compound chemistry Antimony Yield (chemistry) Materials Chemistry Fluoride Arsenic
Zdroj:	Journal of Inorganic and Nuclear Chemistry. 43:1469-1471
ISSN:	0022-1902
Popis:	Tris(t-butylthio) derivatives of arsenic, antimony and bismuth have been prepared in high yield by the reaction of metal fluoride with (t-butylthio)trimethylsilane. The products have been characterized by elemental analysis, IR, Raman, proton NMR and mass spectrometry. Attempts to prepare As(V), Sb(V) or S(IV) derivatives were unsuccessful, although the reaction of SF4 or Et2NSF3 suggests the formation of S(IV) intermediates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f4411da389e3bfbb53471dadf54b1597 https://doi.org/10.1016/0022-1902(81)80318-1 Zobrazit plný text záznamu