Isomerization in olefin formation in radiation degradation of poly(olefin sulphone)s
| Autor: | Trevor N. Bowmer, Peter R. Wells, James H. O'Donnell |
|---|---|
| Rok vydání: | 1980 |
| Předmět: |
chemistry.chemical_classification
Olefin fiber Materials science Polymers and Plastics Hydride General Chemistry Polymer Condensed Matter Physics Photochemistry Water-gas shift reaction Radiation degradation chemistry Polymer chemistry Materials Chemistry Olefin formation Isomerization Bond cleavage |
| Zdroj: | Polymer Bulletin. 2:103-110 |
| ISSN: | 1436-2449 0170-0839 |
| DOI: | 10.1007/bf01033384 |
| Popis: | Gamma irradiation of poly(3-methyl-1-butene sulphone) in the solid state at 20°C produced a mixture of isomers, viz. 3-methyl-1-butene (61%), 2-methyl-1-butene (2%) and 2-methyl-2-butene (37%). Similarly, poly(1-butene sulphone) yielded 1-butene (65%) and 2-butene (35%). A hydride shift reaction in a polymer cation produced by main-chain scission is proposed to account for the isomerization. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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