Nucleophilic Substitution Reactions of O-Methyl N,N-Diisopropylamino Phosphonochloridothioate with Anilines and Pyridines

Autor:	Hai Whang Lee, Hasi Rani Barai
Rok vydání:	2014
Předmět:	chemistry.chemical_compound Chemistry Nucleophilic substitution Organic chemistry General Chemistry Free-energy relationship Kinetic energy Acetonitrile Medicinal chemistry
Zdroj:	Bulletin of the Korean Chemical Society. 35:1016-1022
ISSN:	0253-2964
Popis:	E-mail: hwlee@inha.ac.krReceived November 22, 2013, Accepted December 5, 2013The kinetic studies on the reactions of O-methyl N,N-diisopropylamino phosphonochloridothioate with X-anilines and X-pyridines have been carried out in acetonitrile. The free energy relationship with X in theanilines exhibits biphasic concave upwards with a break region between X = (H and 4-F), giving unusualnegative β
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f41b51756c57259c317f6bce9f653444 https://doi.org/10.5012/bkcs.2014.35.4.1016 Zobrazit plný text záznamu