ChemInform Abstract: Octafluorocyclohexa Derivatives of [60]Fullerene: C60(C4F8)n (n = 2, 3, 4, and 6)

Autor:	Lev N. Sidorov, Erhard Kemnitz, Anna S. Pimenova, Sergey I. Troyanov, Pavel A. Khavrel, N. I. Gruzinskaya
Rok vydání:	2010
Předmět:	Fullerene derivatives Fullerene Chemistry Polymer chemistry Molecule General Medicine High-performance liquid chromatography Adduct
Zdroj:	ChemInform. 42
ISSN:	0931-7597
DOI:	10.1002/chin.201102104
Popis:	Fluorocyclohexa adducts C60(C4F8)n were synthesized by high-temperature reaction of fullerene C60 with 1,2-C2F4I2 or 1,4-C4F8I2 in sealed tubes. Their separation by HPLC allowed us to determine molecular structure (X-ray diffraction) of four new compounds C6(C4F8)n (n = 2, 3, 4, and 6). Structures of isomers C60(C4F8)n were discussed in terms of a concept of consecutive addition of C4F8 groups to the fullerene cage.
Databáze:	OpenAIRE
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