| Popis: |
Quartz veins in porphyry copper deposits record the physiochemical evolution of fluids in subvolcanic magmatic-hydrothermal systems. We have combined cathodoluminescence (CL) petrography with fluid-inclusion microthermometry to unravel the growth history of individual quartz veins and to link this history to copper ore formation at Bingham, Utah. Early barren quartz veins with K-feldspar + biotite (potassic) alteration selvages occur throughout the 2 km vertical exposure of quartz monzonite porphyry stock. At depths of 500 m to at least 1350 m below the orebody, fluid inclusions in these barren veins trapped a single-phase CO 2 -bearing fluid containing ∼2-12 wt% NaCl e q u i v . Within and to depths of 500 m below the orebody, early quartz veins contain abundant hypersaline liquid (38-50 wt% NaCl e q u i v ) and vapor-rich inclusions trapped together at temperatures of 560-350 °C and pressures of 550-140 bar, consistent with fluctuations between lithostatic and hydrostatic pressure at paleodepths of 1.4 to 2.1 km. CL petrography shows that bornite and chalcopyrite were deposited together with a later generation of quartz and K-feldspar in microscopic fractures and dissolution vugs in early barren quartz veins and wall rock. This late quartz contains hypersaline liquid (36-46 wt% NaCl e q u i v ) and vapor-rich inclusions trapped at 380-330 °C and at 160-120 bar hydrostatic pressure. We conclude that a single-phase magmatic-hydrothermal fluid underwent phase separation to hypersaline liquid (or brine) and vapor ∼500 m below the base of the orebody at a paleodepth of ∼2.5 km. Brine and vapor continued to ascend and formed multiple generations of barren quartz veins with potassic selvages. Thermal decline to temperatures below 400 °C was the main driving force for copper-iron sulfide deposition, given the lack of evidence of mixing of brines with low-salinity waters, the lack of correspondence of the ore zone with the initiation of phase separation, and no change in wall-rock alteration style. |
