| Popis: |
The structure of the rotator phase and the phase transitions in n‐alcohols C17, C18, and their mixtures are studied by differential scanning calorimetry (DSC) and by x‐ray diffraction. Both the heating and cooling phase diagrams of the binary system are determined. During cooling, a new intermediate phase α’ is observed under a temperature region of the usual rotator phase α. These α and α’ phases are found to correspond to the rotator‐II phase and the rotator‐I phase, respectively, of n‐paraffins. The dynamical crystal structure in the α phase is revealed by investigation of the diffuse scattering from the single crystal. The characteristic diffuse scattering observed originates from molecular fluctuations due to the translation along and the rotation around the molecular axes. Both modes of the molecular motions are studied separately from the diffuse scattering on the first and on the second layer lines. The translational disorder is described by the averaged relative translation between the nearest ne... |
Plný text