Order-disorder phase transition in the peroxidovanadium complex NH4[VO(O2)2(NH3)]
| Autor: | Přemysl Vaněk, Róbert Gyepes, Peter Schwendt, Jana Chrappová, Ivan Němec |
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| Rok vydání: | 2018 |
| Předmět: |
Phase transition
Chemistry 02 engineering and technology Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Analytical Chemistry Ion symbols.namesake Molecular vibration symbols Physical chemistry Molecule Orthorhombic crystal system 0210 nano-technology Raman spectroscopy Instrumentation Spectroscopy Basis set |
| Zdroj: | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 200:110-115 |
| ISSN: | 1386-1425 |
| DOI: | 10.1016/j.saa.2018.04.019 |
| Popis: | Complex NH4[VO(O2)2(NH3)] (1) undergoes an order-disorder phase transition at Tc ~ 258 K. This transition is accompanied by change in the space group of the orthorhombic lattice and also by significant structural rearrangements of the constituent molecules, which are pertinent mostly to their NH4+ ions and their ammonia ligands. The low-temperature solid state IR and Raman spectra of 1 were corroborated by solid-state computations that employed Gaussian functions as the basis set. Results of these computations yielded excellent agreement with experimental data. On the curves of temperature dependence of vibrational modes, the phase transition is expressed by an abrupt change of the slope above Tc. |
| Databáze: | OpenAIRE |
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