Synthesis, Characterization, and Photophysical Studies of New Blue Light Emitting Segmented Copolymers

Autor:	Ananda M. Sarker, Min Zheng, E. Elif Gürel, Frank E. Karasz, Paul M. Lahti
Rok vydání:	2001
Předmět:	chemistry.chemical_classification Photoluminescence Polymers and Plastics Absorption spectroscopy Chemistry Organic Chemistry Condensation Polymer Chromophore Electroluminescence Inorganic Chemistry Wittig reaction Polymer chemistry Materials Chemistry Copolymer
Zdroj:	Macromolecules. 34:5897-5901
ISSN:	1520-5835 0024-9297
Popis:	A series of new segmented copolymers containing m-phenylene in the chromophore unit have been synthesized by Wittig condensation. They are readily soluble in organic solvents and have high photoluminescence quantum yields in chloroform. Face-to-face π-stacking in the solid state is limited or prevented by molecular nonlinearity due to the meta-linkage and by the presence of a bulky tert-butyl group in the chromophores. Single-layer electroluminescence devices with an ITO/polymer/Ca−Al configuration emitted in the blue region (470−490 nm) for all of these systems.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f3f2542d8303a09083aeb657d87c5d94 https://doi.org/10.1021/ma010071y Zobrazit plný text záznamu