A laser spectroscopic study of gas‐phase TiH

Autor:	Benoit Simard, Peter A. Hackett, M. Vasseur, Jeffrey E. Shirley, Timothy C. Steimle
Rok vydání:	1991
Předmět:	Chemistry Analytical chemistry General Physics and Astronomy Laser law.invention Dipole symbols.namesake Stark effect law Excited state symbols Physical and Theoretical Chemistry Atomic physics Spectroscopy Laser-induced fluorescence Molecular beam Visible spectrum
Zdroj:	The Journal of Chemical Physics. 95:7179-7182
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.461394
Popis:	The results of the first laser spectroscopic study of gas‐phase titanium monohydride, TiH, are described. Survey laser induced fluorescence (LIF) scans over an extensive region of the visible spectrum revealed no new band systems that could be attributed to TiH. The known band system at 535 nm was studied by Doppler limited LIF, sub‐Doppler LIF, and sub‐Doppler/Stark LIF techniques. The 535 nm optical features are consistent with an assignment to the X 4Φ(Ω=3/2)–4Γ(Ω=5/2) subband. The permanent electric dipole moments of 2.998 and 2.455 D were determined for the excited and ground states, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f3ed15b797c14725957a6d4ae3da789a https://doi.org/10.1063/1.461394 Zobrazit plný text záznamu