Limits of Detection of Chemical Elements in an Aqueous Aerosol in Filament-Induced Breakdown Spectroscopy
Autor: | V. V. Lisitsa, O. A. Bukin, A. Yu. Mayor, A. A. Ilyin, Yu. S. Tolstonogova, Sergey S. Golik, Anton V. Borovskiy |
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Rok vydání: | 2021 |
Předmět: |
Detection limit
Aqueous solution Materials science 010401 analytical chemistry Analytical chemistry 02 engineering and technology 021001 nanoscience & nanotechnology Condensed Matter Physics Laser 01 natural sciences 0104 chemical sciences Aerosol law.invention law Excited state Femtosecond Emission spectrum 0210 nano-technology Spectroscopy |
Zdroj: | Journal of Applied Spectroscopy. 88:337-342 |
ISSN: | 1573-8647 0021-9037 |
Popis: | The capabilities of filament-induced breakdown spectroscopy for the analysis of the elemental composition of aqueous aerosols were estimated. The diameter of aqueous aerosol droplets in the atmosphere was 0.8–2.0 μm. The emission lines of the chemical elements were excited by fi lamentation of femtosecond laser pulses (60 fs, 800 nm, 4.4 mJ) in weak focusing mode by a lens with a focal length of 500 mm. The obtained limits of detection for Al (396.15 nm), Ba (553.35 nm), Ca (422.67 nm), Mg (285.21 nm), Na (588.99 nm), and Mn (403.08 nm) in an aqueous aerosol were 12.1, 41.7, 10.0, 7.3, 0.7, and 32.3 mg/L, respectively. |
Databáze: | OpenAIRE |
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