Efficient synthetic procedure to new 2-imino-1,3-thiazolines and thiazolidin-4-ones promoted by acetonitrile electrogenerated base
| Autor: | Hana Ayari, Belen Batanero, Beya Haouas, Najwa Sbei, M. Lamine Benkhoud |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Base (chemistry) 010405 organic chemistry Regioselectivity General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry Yield (chemistry) Materials Chemistry High current Acetonitrile |
| Zdroj: | New Journal of Chemistry. 42:11776-11781 |
| ISSN: | 1369-9261 1144-0546 |
| DOI: | 10.1039/c8nj01992d |
| Popis: | A novel and convenient strategy is described for the regioselective conversion of N,N′-disubstituted thioureas and 1,2-dielectrophiles into the highly biologically valuable 2-imino-thiazoline and 2-imino thiazolidine-4-one derivatives. The synthesis proceeds through a process with good yield promoted by an electrogenerated base (EGB) obtained with high current efficiency. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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