3,4-Pyrazino-3',4'-ethylenedithio-2,2',5,5'-tetrathiafulvalenium Tetraiodothallate(III) Solvate (3:1) with 1,1,2-Trichloroethane, (PEDT–TTF)3TlI4.TCE

Autor:	John A. Schlueter, Urs Geiser, A. S. Komosa, Jack M. Williams, Crystal A. Achenbach, A. M. Kini
Rok vydání:	1996
Předmět:	1 1 2-Trichloroethane Bicyclic molecule Stereochemistry Intermolecular force Crystal growth General Medicine Crystal structure General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound Crystallography chemistry Molecule Transverse direction Tetrathiafulvalene
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 52:159-162
ISSN:	0108-2701
Popis:	The organic donor molecule PEDT-TTF (3,4-pyrazino-3',4'-ethylenedithio-2,2',5,5'-tetrathiafulvalene) forms a semiconducting 3 :1 solvate salt with TlI 4 - in TCE (1,1,2-trichloroethane), (C 10 H 6 N 2 S 6 ) 3 + .TlI 4 - .C 2 H 3 Cl 3 . Its crystal structure contains stacks with six sinusoidally displaced PEDT-TTF molecules per repeat unit. However, the topology of short intermolecular S...S interactions is one dimensional in the transverse direction which coincides with the direction of the most developed crystal growth.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f3ce2b20ce1be66cd08dcbbf8e1c1f1a https://doi.org/10.1107/s0108270195010079 Zobrazit plný text záznamu Plný text