Diffusion coefficient and interatomic potential of He–Ar at high temperatures

Autor: J. J. Hurly, W. L. Taylor, F. R. Meeks, S. B. Wyrick
Rok vydání: 1990
Předmět:
Zdroj: The Journal of Chemical Physics. 92:6786-6793
ISSN: 1089-7690
0021-9606
DOI: 10.1063/1.458265
Popis: Measurements of the mutual diffusion coefficient D12 for the He/Ar gaseous system have been extended to 2050 K, approximately 600 deg beyond any previous work. The results, obtained in a tungsten–tantalum–hafnium alloy (‘‘T‐111’’) two‐bulb cell, are in excellent agreement with previous studies in the 200–1400 K range. An equation is presented which has been fitted to all available published D12 results. An HFD‐B interatomic potential is proposed which accurately predicts D12 within accepted experimental uncertainties.
Databáze: OpenAIRE