ChemInform Abstract: A New Chain-Like Heteropolytungstate Formed by Keggin Cluster Units: Synthesis and Structure of [H2bpy]3[SiMnW11O39]×1.25H2O
Autor: | Enbo Wang, Jing Xin Meng, Yang Guang Li, Ying Ma, Xinxin Xu |
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Rok vydání: | 2008 |
Předmět: | |
Zdroj: | ChemInform. 39 |
ISSN: | 1522-2667 0931-7597 |
Popis: | A new heteropolytungstate, [H 2 bpy] 3 [SiMnW 11 O 39 ]·1.25H 2 O ( 1 ), has been prepared under mild hydrothermal conditions and structurally characterized by single crystal X-ray diffraction. It is the first characterized compound containing 1D zigzag chain of transition metal substituted Keggin heteropolytungstate, which is connected through a common oxygen atom. The elemental analysis and IR of it are also described. |
Databáze: | OpenAIRE |
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