ChemInform Abstract: A New, Improved and Convenient Synthesis of 4H-Cyclopenta[2,1-b:3,4-b′]dithiophen-4-one

Autor:	John R. Reynolds, J. Z. Brzezinski
Rok vydání:	2010
Předmět:	Coupling (electronics) chemistry.chemical_classification chemistry.chemical_compound Ketone Chemistry Organic chemistry General Medicine Methanol Medicinal chemistry Thiophene derivatives
Zdroj:	ChemInform. 33
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200239104
Popis:	A new and efficient three-step synthesis of 4H-cyclopenta[2,1-b:3,4-b']dithiophen--4-one (CDT) (1) is described. This was achieved by a one-pot, regiospecific synthesis of bis(2-iodo-3-thienyl)methanol (13), its subsequent oxidation to the bis(2-iodo-3-thienyl) ketone (14) which after Ullmann coupling yielded the title compound 1.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f36e2fa1062cd4724e1b92e53fbfe463 https://doi.org/10.1002/chin.200239104 Zobrazit plný text záznamu Plný text