Microwave Dielectric Properties of LiKSm2 (MoO4 )4 Ceramics with Ultralow Sintering Temperatures

Autor: Di Zhou, Hai-Hong Xi, Jun Han, Wen-Bo Li, Xu Zheng, Xiao-Liu Zhai
Rok vydání: 2015
Předmět:
Zdroj: Journal of the American Ceramic Society. 98:2716-2719
ISSN: 0002-7820
DOI: 10.1111/jace.13759
Popis: In this work, a novel low-temperature firing microwave dielectric ceramic LiKSm2(MoO4)4 was prepared via solid-state reaction method. Ceramic samples with relative densities about 94.6% were obtained at sintering temperature 640°C–680°C. The best microwave dielectric properties was obtained in ceramic sample sintered at 620°C with a permittivity about 11.5, a Q × f value about 39 000 GHz and a temperature coefficient of frequency about −15.9 ppm/°C. According to XRD patterns and backscattered electron micrograph, combined with Energy Dispersive Spectra analysis, of cofired samples with 30 wt% aluminum sintered at 620°C/4 h, the LiKSm2(MoO4)4 ceramic was found to be chemically compatible with Al but react seriously with Ag, forming AgSmMo2O8 phase, at its sintering temperature.
Databáze: OpenAIRE