Synthesis of 2-(β-Hetarylaminoethyl)-3,5,6-trichloro-1,4-benzoquinones

Autor:	Raimonds Valters, G. Karlivans
Rok vydání:	2004
Předmět:	chemistry.chemical_compound chemistry Furan Intramolecular force Organic chemistry Charge (physics) General Medicine Ring (chemistry) Medicinal chemistry
Zdroj:	ChemInform. 35
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200442096
Popis:	4,6,7-Trichloro-2-hetarylamino-5-hydroxy-2,3-dihydrobenzo[b]furans have been prepared from 4,6,7-trichloro-2,5-dihydroxy-2,3-dihydrobenzo[b]furan and hetarylamines. Reductive opening of the dihydrobenzofuran ring in these compounds gave 3,5,6-trichloro-2-(β-hetarylaminoethyl)hydroquinones. The latter could be oxidised to the target 3,5,6-trichloro-2-(β-hetarylaminoethyl)-1,4-benzoquinones which are novel 1,4-benzoquinone derivatives with intramolecular charge transfer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f3610db488441facc056ec2323b541d5 https://doi.org/10.1002/chin.200442096 Zobrazit plný text záznamu Plný text