Umpolung of Tropone: Preparation of 2-Aroyl- and 2-Acyltropones

Autor: Hiroyuki Miyano, Tohru Takayasu, Makoto Nitta, Hiroshi Horikoshi
Rok vydání: 1999
Předmět:
Zdroj: Synthetic Communications. 29:4367-4373
ISSN: 1532-2432
0039-7911
DOI: 10.1080/00397919908086599
Popis: The reaction of 2-chlorotropone with DIBAH followed by aldolization with several aldehydes affords 2-(1-hydroxyalkyl)tropones, subsequent oxidation of which results in the formation of 2-aroyl- and 2-acyltropones.
Databáze: OpenAIRE