Umpolung of Tropone: Preparation of 2-Aroyl- and 2-Acyltropones
Autor: | Hiroyuki Miyano, Tohru Takayasu, Makoto Nitta, Hiroshi Horikoshi |
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Rok vydání: | 1999 |
Předmět: | |
Zdroj: | Synthetic Communications. 29:4367-4373 |
ISSN: | 1532-2432 0039-7911 |
DOI: | 10.1080/00397919908086599 |
Popis: | The reaction of 2-chlorotropone with DIBAH followed by aldolization with several aldehydes affords 2-(1-hydroxyalkyl)tropones, subsequent oxidation of which results in the formation of 2-aroyl- and 2-acyltropones. |
Databáze: | OpenAIRE |
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