Silver(I) coordination polymer based on anthraquinone-2,6-disulfonate: synthesis, crystal structure, and luminescent properties

Autor:	Ji-Jiang Wang, Xiang-Yang Hou, Long Tang, Xiao Wang, Feng Fu, Ya-Pan Wu
Rok vydání:	2012
Předmět:	chemistry.chemical_classification Chemistry Coordination polymer Inorganic chemistry Infrared spectroscopy Polymer Crystal structure Anthraquinone Coordination complex chemistry.chemical_compound Sulfonate Polymer chemistry Materials Chemistry Physical and Theoretical Chemistry Luminescence
Zdroj:	Journal of Coordination Chemistry. 65:2935-2944
ISSN:	1029-0389 0095-8972
Popis:	Self-assembly of anthraquinone-2,6-disulfonic acid disodium salt (Na2a-2,6-dad) and AgNO3 under hydrothermal conditions resulted in an unprecedented coordination complex, which was characterized by single-crystal X-ray analyses, elemental analyses, IR spectra, TG analyses, and fluorescence investigations. Complex 1 is a 3-D coordination polymer, where a-2,6-dad and Ag–Ag bonds play vital roles. Two sulfonate groups of a-2,6-dad are μ 4- and μ 5-bridges. The unique packing environments of the Ag ions and Ag–Ag bonds lead to 1-D chains consisting of eight- and four-membered rings for Ag1 and Ag1, Ag2 and Ag2 connection, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f34aa47a4c7c75b2e7f48365c92fa208 https://doi.org/10.1080/00958972.2012.707315 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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