ChemInform Abstract: Synthesis of Functionalized Furans via Gold(I)-Catalyzed Claisen-Type Rearrangement

Autor: Florin M. Istrate, Fabien Gagosz
Rok vydání: 2008
Předmět:
Zdroj: ChemInform. 39
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.200821106
Popis: Gold(I)-catalyzed cyclization of pentenynyl allyl ethers allows the rapid construction of functionalized furans. The concerted oxy-Claisen-type mechanism induces a complete selectivity of the process and allows the easy formation of quaternary centers.
Databáze: OpenAIRE