Reactions of substituted tetramethylcyclopentadienes with molybdenum hexacarbonyl

Autor:	Kaiming Guo, Na Wang, Jin Lin, Zhi-Hong Ma, Xue-Zhong Zheng
Rok vydání:	2013
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Xylene Materials Chemistry Organic chemistry Metal carbonyl Physical and Theoretical Chemistry Medicinal chemistry Molybdenum hexacarbonyl Single Crystal Diffraction
Zdroj:	Inorganica Chimica Acta. 399:126-130
ISSN:	0020-1693
DOI:	10.1016/j.ica.2013.01.010
Popis:	The reactions of the substituted tetramethylcyclopentadienes [C5Me4HR] [R = ethyl (1), n-propyl (2), i-propyl (3), cyclopentyl (4), cyclohexyl (5), 4-NMe2Ph (6)] with Mo(CO)6 in refluxing xylene gave the corresponding dinuclear metal carbonyl complexes [η5-C5Me4R]2Mo2(CO)6 (7–11), while similar treatment of [C5Me4H(4-NMe2Ph)] (6) with Mo(CO)6 afforded an unexpected product [(η5-C5Me4(4-NMe2Ph))MoO2]2(μ-O) (12). All the new complexes were fully characterized. The molecular structures of 7, 8, 11 and 12 have been determined by X-ray single crystal diffraction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f2f2b561ac504153acd8ed9c6951bdab https://doi.org/10.1016/j.ica.2013.01.010 Zobrazit plný text záznamu Full Text from ScienceDirect