Crystal structure of the CuCl2 complex with N',N'-dimethyl-para-tert-butylbenzohydrazide [Cu(n-(t-Bu)C6H4CONHN(Me)2)]Cl2
| Autor: | V. Yu. Gusev, A. V. Radushev |
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| Rok vydání: | 2016 |
| Předmět: |
Denticity
Chemistry Ligand Materials Science (miscellaneous) Dimer chemistry.chemical_element Crystal structure 010402 general chemistry 010403 inorganic & nuclear chemistry Ring (chemistry) 01 natural sciences Copper 0104 chemical sciences Inorganic Chemistry Crystallography Trigonal bipyramidal molecular geometry chemistry.chemical_compound Physical and Theoretical Chemistry Monoclinic crystal system |
| Zdroj: | Russian Journal of Inorganic Chemistry. 61:964-968 |
| ISSN: | 1531-8613 0036-0236 |
| Popis: | The X-ray diffraction analysis of [Cu(p-(t-Bu)C6H4CONHN(Me)2)]Cl2 (I) has been performed. The complex is binuclear. Its structure represents a centrosymmetric dimer. Copper atoms are linked to each other via two bridging chlorine atoms. The copper coordination polyhedron is a distorted trigonal bipyramid. The dialkylhydrazide reagent is a bidentate (O, N(2)) ligand linked to the central atom to form a five-membered chelate ring, which has an envelope conformation with a copper atom in its “flap.” Crystals are monoclinic. |
| Databáze: | OpenAIRE |
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