Reactions of incompletely-condensed silsesquioxanes with pentamethylantimony: a new synthesis of metallasilsesquioxanes with important implications for the chemistry of silica surfaces

Autor:	Joseph W. Ziller, Theodore A. Budzichowski, Frank J. Feher, Kamyar Rahimian
Rok vydání:	1992
Předmět:	Colloid and Surface Chemistry Chemistry Group (periodic table) X-ray crystallography Polymer chemistry Organic chemistry Halide Molecule Reactivity (chemistry) General Chemistry Crystal structure Biochemistry Catalysis
Zdroj:	Journal of the American Chemical Society. 114:3859-3866
ISSN:	1520-5126 0002-7863
Popis:	The reactions of the incompletely condensed polyhedral oligosilsesquioxanes with excess Me 5 Sb result in the formation of the corresponding stibonium-substituted silsesquioxanes. These stibonium siloxides show enhanced reactivity toward main group and transition-metal halide complexes and provide an alternative route for the preparation of metallasilsesquioxanes
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f2cf94c082e9a1796c0cc9cb071a5a7d https://doi.org/10.1021/ja00036a038 Zobrazit plný text záznamu