| Autor: |
Thomas C. McKenzie, Simon J.F. Macdonald, Wesley Hassen |
| Rok vydání: |
1987 |
| Předmět: |
|
| Zdroj: |
Tetrahedron Letters. 28:5435-5436 |
| ISSN: |
0040-4039 |
| DOI: |
10.1016/s0040-4039(00)96747-9 |
| Popis: |
The synthesis of the agylcone of the antibiotic Gilvocardin-M by a sequential Meerwein Diels-Alder route is reported. The D-ring of the agylcone is attached by a halogen atom directed Meerwein arylation reaction and the A-ring is attached by a halogen atom directed Diels-Alder reaction. In the key step the directing chlorine atom is removed by a new thiophenylation reduction sequence. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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