A novel organically templated three-dimensional open framework vanadium tellurite: (NH3CH2CH2NH3)2V2Te6O18
| Autor: | Xiaohong Wang, Chunyan Sun, Lin-Hua Xie, Shuxia Liu, Ninghai Hu, Bo Gao, Chun-Dan Zhang, Hengqing Jia |
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| Rok vydání: | 2005 |
| Předmět: |
Inorganic chemistry
chemistry.chemical_element Space group Vanadium Condensed Matter Physics Electronic Optical and Magnetic Materials Inorganic Chemistry Crystallography chemistry Transition metal Covalent bond Materials Chemistry Ceramics and Composites Hydrothermal synthesis Physical and Theoretical Chemistry Tellurium Single crystal Monoclinic crystal system |
| Zdroj: | Journal of Solid State Chemistry. 178:1825-1829 |
| ISSN: | 0022-4596 |
| DOI: | 10.1016/j.jssc.2005.03.019 |
| Popis: | A novel organically templated vanadium tellurite (NH3CH2CH2NH3)2V2Te6O18 (1) has been hydrothermally synthesized and characterized by elemental analyses, IR, thermal stability analysis, magnetic susceptibilities and single crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system, space group P 2 1 / n , a = 8.891 ( 2 ) A , b = 8.834 ( 2 ) A , c = 15.906 ( 4 ) A , β = 94.789 ( 4 ) ° , V = 1181.5 ( 5 ) A 3 , Z = 2 , R 1 [ I > 2 σ ( I ) ] = 0.0187 , w R 2 [ I > 2 σ ( I ) ] = 0.0482 . Compound 1 exhibits a novel three-dimensional (3D) vanadium tellurite anion framework composed of vanadium, tellurium, and oxygen atoms through covalent bonds, with the [NH3CH2CH2NH3]2+ cations residing in the channels. |
| Databáze: | OpenAIRE |
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