Phosphoric Acid Bridged Cobalt Bis(dicarbollide) Ion as a Highly Efficient Catalyst for the Organocatalytic Hydrogenation of Ketimines

Autor: Kodai Saito, Takahiko Akiyama, Slawomir Janczak, Zbigniew J. Lesnikowski
Rok vydání: 2014
Předmět:
Zdroj: Synlett. 25:795-798
ISSN: 1437-2096
0936-5214
DOI: 10.1055/s-0033-1340847
Popis: The high-yield reduction of aromatic ketimines into amines by using a novel catalyst based on a metallacarborane structure, 8,8′-μ-phosphate[(1,2-dicarba-closo-undecaborane)-3,3′-cobalt(-1)(1′,2′-dicarba-closo-undecaborane)] acid, is described.
Databáze: OpenAIRE