Solvent-induced synthesis of nitrogen-doped hollow carbon spheres with tunable surface morphology for supercapacitors
| Autor: | Feng Liu, Ning Zhang, Lei Liu, Ru-Liang Zhang, Chang-Ce Ke, Ren-Lu Yuan, Shao-Xia Ma |
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| Rok vydání: | 2018 |
| Předmět: |
Supercapacitor
Materials science Morphology (linguistics) Carbonization General Physics and Astronomy chemistry.chemical_element 02 engineering and technology Surfaces and Interfaces General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Capacitance 0104 chemical sciences Surfaces Coatings and Films Solvent chemistry Chemical engineering Particle size 0210 nano-technology Mesoporous material Carbon |
| Zdroj: | Applied Surface Science. 437:271-280 |
| ISSN: | 0169-4332 |
| DOI: | 10.1016/j.apsusc.2017.12.174 |
| Popis: | Nitrogen doped hollow carbon spheres (NHCSs) with tunable surface morphology have been prepared through one-pot carbonization method by using melamine-formaldehyde spheres as template and resorcinol-based resin as carbon precursor in ethanol-water solution. Well-dispersed NHCSs with particle size of 800 nm were obtained and the surface of NHCSs turn from smooth to tough, wrinkled, and finally concave by increasing the ethanol concentration. The fabricated NHCSs possessed high nitrogen content (3.99–4.83%) and hierarchical micro-dual mesoporous structure with surface area range of 265–405 m2 g−1 and total pore volume of 0.18–0.29 cm3 g−1, which contributed to high specific capacitance, excellent rate capability and long cycle life. |
| Databáze: | OpenAIRE |
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