ChemInform Abstract: A New Strategy for the Conversion of Aldehydes into Difluoromethyl Ketones

Autor: Catherine Girol, Charles G. Schelcher, Serge R. Piettre
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 27
ISSN: 0931-7597
DOI: 10.1002/chin.199641071
Popis: A three-step sequence of reactions involving the lithium salt of diethyl difluoromethylphosphonate as a difluoromethyl carrier is shown to efficiently convert aliphatic and arylic aldehydes 2 into difluoromethyl ketones 1 via an unusual carbon-phosphorus bond scission.
Databáze: OpenAIRE