Novel specific carbon–carbon bond formation; substituent and solvent effects associated with hydride addition to aromatic olefins
Autor: | Yoffi Segall, Itshak Granoth, Haim Leader, Rivka Alkabets, Eliezer Rachaman |
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Rok vydání: | 1975 |
Předmět: | |
Zdroj: | J. Chem. Soc., Chem. Commun.. :348-349 |
ISSN: | 0022-4936 |
Popis: | 2,2-Diarylpropanes are conveniently prepared from 1,1-diarylethylenes, lithium aluminium hydride, and anisole in tetrahydrofuran while 1,1-diarylethanes are obtained at 140 °C in bis(methoxyethyl) ether; hydride addition to 1,1-diarylethylenes is decelerated by 2-methyl substituents, and o- and p-methoxy, but not m-methoxy. |
Databáze: | OpenAIRE |
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