Novel specific carbon–carbon bond formation; substituent and solvent effects associated with hydride addition to aromatic olefins

Autor:	Yoffi Segall, Itshak Granoth, Haim Leader, Rivka Alkabets, Eliezer Rachaman
Rok vydání:	1975
Předmět:	chemistry.chemical_classification Hydride Substituent Ether Lithium aluminium hydride Anisole chemistry.chemical_compound chemistry Carbon–carbon bond Polymer chemistry Molecular Medicine Organic chemistry Solvent effects Tetrahydrofuran
Zdroj:	J. Chem. Soc., Chem. Commun.. :348-349
ISSN:	0022-4936
Popis:	2,2-Diarylpropanes are conveniently prepared from 1,1-diarylethylenes, lithium aluminium hydride, and anisole in tetrahydrofuran while 1,1-diarylethanes are obtained at 140 °C in bis(methoxyethyl) ether; hydride addition to 1,1-diarylethylenes is decelerated by 2-methyl substituents, and o- and p-methoxy, but not m-methoxy.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f1e04072c453f72db0f7be9a70951af2 https://doi.org/10.1039/c39750000348 Zobrazit plný text záznamu