The quantum theory of the effects of bound pairs on the transport properties of gases

Autor:	C. F. Curtiss
Rok vydání:	1994
Předmět:	Physics Relative motion General Physics and Astronomy Boltzmann equation Classical limit symbols.namesake Classical mechanics Quantum mechanics Phase space Bound state symbols Physical and Theoretical Chemistry Hamiltonian (quantum mechanics) Quantum Eigenvalues and eigenvectors
Zdroj:	The Journal of Chemical Physics. 101:3117-3126
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.467625
Popis:	A quantum form of the Boltzmann equation which applies to a gas of atoms which interact through a potential with an attractive portion is developed. It is shown that the existence of discrete negative eigenvalues of the Hamiltonian describing the relative motion leads to modifications of the usual equation. It is then shown that in the classical limit, the limit in which ℏ goes to zero, the present results lead to the results previously obtained through a discussion in which the modifications which arise from a potential involving an attraction portion were considered from a classical point of view.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f1b7a30ba20e5048adadc0428be57c85 https://doi.org/10.1063/1.467625 Zobrazit plný text záznamu