Metal–support cooperation in Al(PO3)3-supported platinum nanoparticles for the selective hydrogenolysis of phenols to arenes

Autor:	Hiroki Miura, Kyoko Nozaki, Rio Tsukimura, Xiongjie Jin, Takeshi Aihara, Tetsuya Shishido
Rok vydání:	2021
Předmět:	Process Chemistry and Technology Bioengineering Platinum nanoparticles Heterogeneous catalysis Biorefinery Biochemistry Chemical synthesis Catalysis Metal chemistry.chemical_compound chemistry Hydrogenolysis visual_art visual_art.visual_art_medium Organic chemistry Fine chemical Phenols
Zdroj:	Nature Catalysis. 4:312-321
ISSN:	2520-1158
Popis:	The hydrogenolysis of phenols to yield arenes is of importance to the production of fine chemicals, as well as biorefinery application; however, the conversion of phenols through cleavage of their strong C(sp2)–OH bonds remains a highly challenging task in synthetic chemistry. Here we report the use of Al(PO3)3-supported platinum nanoparticles for the selective hydrogenolysis of a broad range of phenols (including sterically highly demanding phenols and lignin model compounds) to afford arenes under relatively low temperatures (
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f1ad15f745aee9655a432d32f948b319 https://doi.org/10.1038/s41929-021-00598-x Zobrazit plný text záznamu Full text from SpringerLink