Synthesis, extraction, and chromatographic purification of higher empty fullerenes and endohedral gadolinium metallofullerenes

Autor: V. S. Kozlov, M. V. Suyasova, V. T. Lebedev
Rok vydání: 2014
Předmět:
Zdroj: Russian Journal of Applied Chemistry. 87:121-127
ISSN: 1608-3296
1070-4272
Popis: Higher empty and endohedral gadolinium metallofullerenes were prepared by electric arc synthesis, isolated, and separated chromatographically to high degree of purity (99 wt %). The samples obtained were characterized by chromatography, optical spectroscopy, and mass spectrometry. According to small-angle neutron scattering data, the endohedral metallofullerenes in o-xylene form a molecular solution in which the molecules interact to form molecular pairs.
Databáze: OpenAIRE