Symmetrical and difunctional substituted cobalt phthalocyanines with benzoic acids fragments: Synthesis and catalytic activity

Autor:	Vladimir Maizlish, Serafima Znoyko, Artur Vashurin, Anastasiya Morozova, Oscar I. Koifman, Mikhail Razumov, Ilya Kuzmin
Rok vydání:	2017
Předmět:	010405 organic chemistry Chemistry Sodium Spectral properties chemistry.chemical_element General Chemistry Template synthesis 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis chemistry.chemical_compound Nucleophilic substitution Organic chemistry Cobalt Benzoic acid
Zdroj:	Journal of Porphyrins and Phthalocyanines. 21:37-47
ISSN:	1099-1409 1088-4246
DOI:	10.1142/s108842461750002x
Popis:	Difunctional and symmetric phthalonitriles were synthesized by nucleophilic substitution of brome and nitro-group in 4-bromo-5-nitro-phthalonitrile for residues 4-amino-, 4-hydroxyl- and 4-sulfanyl benzoic acid. Symmetrical and difunctional substituted cobalt phthalocyanines were obtained by template synthesis based on mentioned phthalonitriles. Their spectral properties and catalytic activity in aerobic oxidation of sodium [Formula: see text],[Formula: see text]-carbomoditiolate were investigated.
Databáze:	OpenAIRE
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