Towards strongly correlated semimetals: U2Ru2Sn and Eu8Ga16Ge30

Autor: André M. Strydom, V.H. Tran, P. de V. du Plessis, Frank Steglich, A. Rabis, Michael Baenitz, Wilder Carrillo-Cabrera, Silke Paschen, Yu. Grin
Rok vydání: 2002
Předmět:
Zdroj: Journal of Physics and Chemistry of Solids. 63:1183-1188
ISSN: 0022-3697
DOI: 10.1016/s0022-3697(02)00160-9
Popis: We present results of transport, magnetic, and calorimetric measurements on two f-electron based compounds: U 2 Ru 2 Sn and Eu 8 Ga 16 Ge 30 . We show that U 2 Ru 2 Sn shares several properties with the strongly correlated semimetal CeNiSn. These analogies suggest that in U 2 Ru 2 Sn a narrow energy gap (or pseudogap) opens which is one order of magnitude larger than the one of CeNiSn. The two modifications of the clathrate Eu 8 Ga 16 Ge 30 behave as local-moment ferromagnetic metals with relatively low Curie temperatures and small charge-carrier concentrations. The thermal conductivity is low and glass-like, as expected for filled-cage' systems. If, by modification of the Ga-Ge cages, a 'Kondo insulating' ground state could be realized, a high thermoelectric figure of merit associated with the (pseudo)gap opening would be expected.
Databáze: OpenAIRE