ChemInform Abstract: Modified Synthesis of Monocyclic 1,2,3-Triazine and Cycloaddition Reaction with Enamine: The Application to the Synthesis of Alkaloids, Tortuosamine, N-Formyltortuosamine, and N-Acetyltortuosamine

Autor: Kiyoshi Tagahara, T. Okatani, Junko Koyama
Rok vydání: 1990
Předmět:
Zdroj: ChemInform. 21
ISSN: 0931-7597
DOI: 10.1002/chin.199012339
Popis: Monocyclic 1,2,3-triazines were obtained by periodate oxidation of 1-aminopyrazoles in good reproducibilities and yields. The Diels-Alder reaction of 1,2,3-triazine with several enamines was carried out to afford 2,3-disubstituted pyridines. As an application of this method, we accomplished the synthesis of alkaloids, tortuosamine, N-formyltortuosamine and N-acetyltortuosamine
Databáze: OpenAIRE