Hydrolysis of 2-alkoxyalk-2-enals

Autor: M. G. Voronkov, G. I. Sarapulova, Natalia A. Keiko, T. N. Mamashvili
Rok vydání: 1998
Předmět:
Zdroj: Russian Chemical Bulletin. 47:2465-2467
ISSN: 1573-9171
1066-5285
Popis: Hydrolysis of 2-alkoxyalk-2-enals with equimolar amount of water (in an organic solvent) and with an excess of water has been studied with the aim of synthesizing 2-oxopropanal (methylglyoxal). 2-Oxopropanal obtained in an excess of water exists in the hydrate from. In organic solvents, the cyclic trimer of 2-oxopropanal, 2,4,6-triacetyl-1,3,5-trioxane, predominates (NMR data).
Databáze: OpenAIRE