Aromatic chloroosmacyclopentatrienes
| Autor: | Zhenwei Chu, Guomei He, Chuan Shi, Yuhui Hua, Yaxi Huang, Jiangxi Chen, Hujun Xie, Guochen Jia |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | National Science Review. 10 |
| ISSN: | 2053-714X 2095-5138 |
| Popis: | Aromatic metallacycles are of considerable current interest. Reported aromatic metallacycles are mainly those with carbon, nitrogen, oxygen and sulfur. In this work, we report the synthesis and characterization of aromatic chloroosmacyclopentatrienes, which represent the first structurally confirmed metallaaromatic with a chlorine atom in its framework. Single-crystal X-ray diffraction studies show that these planar chloroosmacyclopentatrienes possess a very short Os–ClC distance suggesting M=ClC bond character. |
| Databáze: | OpenAIRE |
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