ChemInform Abstract: Indium-Catalyzed Reductive Sulfidation of Aromatic Carboxylic Acids and Aldehydes with Elemental Sulfur to Prepare Symmetrical Benzyl Sulfides

Autor:	Shunsuke Yoshimoto, Yohei Ogiwara, Kota Nishino, Takahiro Miyazaki, Norio Sakai
Rok vydání:	2015
Předmět:	Metal chemistry visual_art Reagent Polymer chemistry visual_art.visual_art_medium Sulfidation chemistry.chemical_element General Medicine Sulfur Indium Catalysis
Zdroj:	ChemInform. 46
ISSN:	0931-7597
DOI:	10.1002/chin.201530117
Popis:	Described herein is a direct approach to symmetrical thioethers from either aromatic carboxylic acids or aromatic aldehydes with elemental sulfur (S8) by using a reducing system combined with InI3 and 1,1,3,3-tetramethyldisiloxane (TMDS). This sulfidation does not require functionalized sulfur reagents, such as sulfides, disulfides, or metal sulfides, and it simultaneously forms two carbon–sulfur bonds in a single catalytic system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f16c2f1629ef5fb73cc69c83c769b3e6 https://doi.org/10.1002/chin.201530117 Zobrazit plný text záznamu Plný text