Sodium borohydride reduction of aldehydes catalyzed by an oxovanadium(IV) Schiff base complex encapsulated in the nanocavity of zeolite-Y

Autor:	Elaheh Bohloulbandi, Saeed Rayati, Saeed Zakavi
Rok vydání:	2015
Předmět:	chemistry.chemical_classification Ketone Schiff base Aldehyde Inorganic Chemistry Sodium borohydride chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Organic chemistry Selective reduction Physical and Theoretical Chemistry Chemoselectivity Zeolite Acetophenone
Zdroj:	Inorganic Chemistry Communications. 54:38-40
ISSN:	1387-7003
Popis:	Selective reduction of a wide range of aromatic and aliphatic aldehydes to the corresponding alcohols with NaBH4 was achieved in the presence of an oxovanadium(IV) Schiff base complex encapsulated in the nanopores of zeolite Y (VOL-Y). For most of the aldehydes, a conversion of 100% was observed after less than 5 min. High chemoselectivity of the reduction for aldehydes over ketones was verified by a competitive reduction between 4-methylbenzaldehyde and acetophenone.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f167fdd72cd9f0d5b4553d1cd508c732 https://doi.org/10.1016/j.inoche.2015.02.004 Zobrazit plný text záznamu Full Text from ScienceDirect