Photooxidation of Perfluoroethyl Iodide and Perfluoro-n-propyl Iodide1a

Autor:	Dana G. Marsh, Julian Heicklen
Rok vydání:	1966
Předmět:	chemistry.chemical_classification Chemical kinetics Chemistry Iodide General Engineering chemistry.chemical_element Quantum yield Physical and Theoretical Chemistry Photochemistry Iodine Oxygen Iodine compounds
Zdroj:	The Journal of Physical Chemistry. 70:3008-3010
ISSN:	1541-5740 0022-3654
DOI:	10.1021/j100881a505
Popis:	Perfluoroethyl iodide and perfluoro-propyl iodide were photolyzed in the presence of oxygen. In both cases, the major product is CF2O. In the C2F5I system, it is produced with a quantum yield of about 2.0. CF3CFO is also produced, but is 100 times less important. With HI present, the oxidation is drastically modified, and the RO2 intermediate must live at least 10 to the minus 7th power second. (Author)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f163a5eff3a9e9a75cde3f9b4b4485b8 https://doi.org/10.1021/j100881a505 Zobrazit plný text záznamu