Patterns of phenol oxidation process with an aqueous solution of hydrogen peroxide
| Autor: | M. E. Fedosova, A. E. Fedosov, S. M. Danov, A. I. Shishkin, S. V. Orekhov |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Catechol
Aqueous solution Hydroquinone Chemistry General Chemical Engineering Inorganic chemistry chemistry.chemical_element 02 engineering and technology General Chemistry 021001 nanoscience & nanotechnology Catalysis chemistry.chemical_compound 020401 chemical engineering Phenol 0204 chemical engineering 0210 nano-technology Hydrogen peroxide Selectivity Titanium |
| Zdroj: | Theoretical Foundations of Chemical Engineering. 50:525-529 |
| ISSN: | 1608-3431 0040-5795 |
| Popis: | This paper presents experimental data on the study of catalytic systems based on titanium silicalite (TS-1) for liquid-phase oxidation of phenol. The influence of the main parameters of the process of liquid phase oxidation of phenol with aqueous solution of hydrogen peroxide on the catalyst; the formed titanium silicalite (initial molar ratio of phenol/hydrogen peroxide, temperature) has been studied based on the basic parameters of the process, including the degree of conversion of hydrogen peroxide, the degree of conversion of phenol, the selectivity of the formation of catechol, hydroquinone and 1,4-benzoquinone, and the ratio of products in the reaction mass. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|