ChemInform Abstract: Synthesis of 1,3-Bisubstituted p-t-Butylcalix[4]crowns Containing an Ethylene
Autor: | Rui-Sen Lin, Ping-Shan Wang |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 30 |
ISSN: | 1522-2667 0931-7597 |
Popis: | 1.3-bisubstituted calix[4]crown 2 containing an ethylene was synthesized from p-t-butylcalix[4]arene 1 and 1, 2-dibromoethene in the presence of K2CO3. 2 was modified by 2+2' functional group disposition to produce the distal diether 3a in a 72% yield and selectively ipso-nitrated to give 3b in 61% yield. |
Databáze: | OpenAIRE |
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