Electrochemical behaviour of α- and β-PbO2 Part II: Lithium diffusion from non-aqueous electrolyte

Autor:	N. Chelali, J. Guitton, A. Hammouche, L. Zerroual, A. Kahoul
Rok vydání:	1996
Předmět:	Reaction mechanism Stereochemistry Diffusion Analytical chemistry chemistry.chemical_element Lead dioxide General Chemistry Aqueous electrolyte Condensed Matter Physics Electrochemistry Lithium perchlorate Ion chemistry.chemical_compound chemistry General Materials Science Lithium
Zdroj:	Solid State Ionics. 91:289-294
ISSN:	0167-2738
DOI:	10.1016/s0167-2738(96)00423-7
Popis:	The cathodic behaviour of α- and β-PbO 2 was studied in the presence of lithium ions using slow-scan voltametry. The β-PbO 2 shows two peaks at 2.95 V and 2.45 V versus Li/Li + . However, in the case of α-PbO 2 , similar peaks appear at 2.74 V and 2.35 V versus Li/Li + . The values of D Li + calculated for both samples were 5 × 10 −13 cm 2 s −1 for α-PbO 2 and 10 −14 cm 2 s −1 for β-PbO 2 . The α phase seems to be a better lithium conductor than the β phase.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f145718fc1c86c734fc07867ea0ebebc https://doi.org/10.1016/s0167-2738(96)00423-7 Zobrazit plný text záznamu Full Text from ScienceDirect