Chemiluminescence from tetramethyldioxetane in poly(methyl methacrylate) and polystyrene
| Autor: | Jozef Rychlý, Rastislav Broska, L. Matisová-Rychlá |
|---|---|
| Rok vydání: | 1996 |
| Předmět: |
Polymers and Plastics
Organic Chemistry Thermal decomposition Kinetics General Physics and Astronomy Poly(methyl methacrylate) Isothermal process law.invention Matrix (chemical analysis) chemistry.chemical_compound chemistry law Excited state visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Physical chemistry Polystyrene Chemiluminescence |
| Zdroj: | European Polymer Journal. 32:1251-1256 |
| ISSN: | 0014-3057 |
| DOI: | 10.1016/s0014-3057(96)00099-7 |
| Popis: | The kinetics of chemiluminescence accompanying the thermal decomposition of tetramethyl-1,2-dioxetane (TMD) in a polymethyl methacrylate matrix and a polystyrene matrix has been investigated at isothermal and non-isothermal conditions. Induced decomposition of TMD by excited activator—9,10-dibromoanthracene (DBA)—has been observed for a PMMA matrix and the energy transfer radius for this process has been estimated. The different values of activation parameters obtained by both methods are discussed. |
| Databáze: | OpenAIRE |
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